“modern physical organic chemistry” by e. anslyn and d. dougherty

Modern Physical Organic Chemistry: Understanding the Fundamentals of Contemporary Chemical Reactions

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In recent years, physical organic chemistry has emerged as a distinct and fascinating branch within the broader field of organic chemistry. This area of study focuses on applying principles from both physical sciences (such as thermodynamics, kinetics, quantum mechanics) to gain deeper insights into chemical reactions occurring at the molecular level.

Eric V Anslyn and Dennis A Dougherty's comprehensive textbook 'Modern Physical Organic Chemistry' provides an authoritative introduction to this rapidly evolving field. Written for advanced undergraduate students and graduate researchers alike, it delves into the theoretical underpinnings of modern physical organic chemistry while also exploring its diverse applications across various areas such as catalysis, supramolecular recognition, photochemistry, electrochemical reactions, etc.

The book begins by establishing a solid foundation in basic concepts including thermodynamics, kinetics, quantum mechanics and molecular orbital theory. It then progresses into more advanced topics like reaction mechanisms, stereochemistry & stereocenter chirality rules for saturated/unsaturated systems; nucleophilic substitution reactions involving inversion of configuration via SN1/SN2 pathways along with E2 elimination processes followed by allylic rearrangement sequences leading up to pericyclic transformations. Other key areas covered include cycloadditions (Diels-Alder reaction), sigmatropic shifts, biradical intermediates formed during radical recombination reactions etc.

Throughout the book, numerous examples are provided throughout each chapter to help readers develop a better understanding of complex concepts through real-world applications. Additionally, end-of-chapter problems and solutions allow students to further solidify their grasp on these intricate topics while also serving as valuable tools for instructors looking to assess student comprehension in class or during exams.

Overall, 'Modern Physical Organic Chemistry' by Eric V Anslyn & Dennis A Dougherty is an indispensable resource for anyone seeking a comprehensive understanding of modern physical organic chemistry. With its clear explanations and numerous examples making even the most complex concepts accessible to readers at all levels of expertise, this book truly lives up to its title as 'the go-to' textbook in today's rapidly changing chemical landscape.

Rating Breakdown

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* 5/5 stars: Highly recommended for advanced undergraduate students & graduate researchers looking for a comprehensive introduction to modern physical organic chemistry.

* 4.25/5 stars: Suitable choice for those already familiar with basic concepts of organic chemistry but seeking an in-depth understanding of more advanced topics such as reaction mechanisms, stereochemistry etc.

Recommended Audience

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- Advanced Undergraduate Students studying Organic Chemistry or related disciplines (Chemistry, Biochemical Engineering)

- Graduate Researchers working towards Ph.D. degrees in areas like Physical Organic Chemistry, Materials Science & Technology

Targeted Skills/Prerequisites:

------------------------------1) Prior knowledge of basic principles from organic chemistry such as thermodynamics, kinetics and quantum mechanics.

2) Familiarity with molecular orbital theory would also be beneficial but not essential.

Overall Assessment

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In conclusion, 'Modern Physical Organic Chemistry' by Eric V Anslyn & Dennis A Dougherty is an outstanding textbook that provides students with a solid foundation in the fundamental principles of modern physical organic chemistry. With its clear explanations and numerous examples making even complex concepts accessible to readers at all levels of expertise, this book truly lives up to its title as 'the go-to' resource for anyone seeking a comprehensive understanding of contemporary chemical reactions.

Price: Starting at $74.60

Publisher: Wiley Blackwell

Publication Date: 4th edition (December 31st, 2022)

Hardcover | 1st ed.; 3rd reprint | ISBN-13:9781118284936

“modern physical organic chemistry” by e. anslyn and d. dougherty